![]() ![]() Above and to the right of the option to change the name is the browser settings, which offers the option to save the archive in any location on the device. Archiver abilitiesīy clicking the 'Add' icon, the WinRAR community can create, and add files to, and archive the archive that the files go into can be established by creating a name under 'Archive name'. Similar to right clicking on the folders, users can extract, and compress, files from within the WinRAR shortcut. Conveniently, WinRAR offers a 'Yes to all' button, allowing users to extract all the files at once into a different location.Īfter double-clicking on WinRAR's shortcut icon, people can navigate the command line options: 'Add', 'Extract to', 'Test', 'View', 'Delete', 'Find', 'Wizard', 'Info', and repair options. Within the pop-up, the 'Extract here' option will extract the files into the same window. One of the ways to extract files from zipped folders is to locate the folder and right click on the icon for the 'Extract' pop-up options.īy clicking on 'Extract files.' within the pop-up options, consumers are prompted to choose a folder to extract the files into within their devices' directories. With WinRAR, the zipped folders are stored within an icon that appears as the company's logo you can unzip these folders by extracting files. When multiple files are downloaded at once, they are stored in zipped folders. The 'Shell integration' options are for accessing WinRAR's features on context menus: 'Add', 'Extract', 'Wizard', etc. Upon installing the tool, users are given interface options: adding the WinRAR icon to the desktop screen or ‘Start Menu’ for easy accessibility, and creating a WinRAR program group. WinRAR supports and formats RAR, ZIP, ACE, ARJ, BZ2, CAB, GZIP, ISO, JAR, LZH, TAR, UUE, XZ, Z, 001 and 7-ZIP files. The application can be downloaded in a multitude of languages: Chinese, English, Catalan, Indonesian, Portuguese, Serbian, Slovenian, etc. WinRAR is available in two versions based on computers' operating systems: the 32-bit and the 64-bit. When the free trial ends, there are windows that regularly pop-up to remind users to purchase a WinRAR license. If the free trial option is chosen, then there are restrictions to the application’s features - which are only available on the licensed version: ‘Add authenticity information’, ‘Show protocol file’, and ‘Delete protocol file’. ![]() Users have the options to download WinRAR with a free trial or purchase the software WinRAR requires a license after the trial period ends. The tool unzips folders by extracting files and uses compression to zip multiple files into one folder. WinRAR is a software created by RARLAB for Windows that is used to extract and compress files. ![]()
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9/6/2023 0 Comments Bridgerton series order![]() ![]() Queen Charlotte (2023) (with Shonda Rhimes)įinally, there are two companion books within this world.This book is based on the popular Shondaland Netflix series: Queen Charlotte: A Bridgerton Story. The Girl with the Make-Believe Husband (2017)īefore the Bridgertons, Queen Charlotte and King George III’s love story sparked societal shift.It will also mean that the appearances of Anthony, Benedict, and Colin as young children will be a delightful Easter egg. This will mean you are already familiar with the world and writing. While you can choose to read the prequels first, it is best to read these books after the main series. The books begin in the early 1790s, meaning these books take place in the Georgian era, not the Regency era. The Rokesbys are neighbors and close friends of the Bridgertons, which is apparent with each book following a new romantic reunion between the families. These books, the Rokesbys series, are prequels to the main Bridgerton books. Each book in the series depicts the love story of a Bridgerton sibling. These are the main Bridgerton books, which is where you should start your Bridgerton reading journey. While a happily-ever-after is almost a guarantee in a romance, it would ruin an element of the suspense or will-they-won’t-they to read about a happily married couple before you experience the tumultuous start to their relationship. Obviously each book follows a new couple, but since the overarching series follows the same close-knit family, protagonists from previous books will be in the background throughout the series. That’s because it is the best way to grow familiar with the world, become fond of the characters, and avoid any spoilers. ![]() Reading the books in publication order is the best way to experience the series. This is the way that millions of fans experienced the books for the first time. The first way you can read the Bridgerton books in order is the recommended reading order if you are just beginning the series. #1 – Bridgerton Books in Order by Publication Read on for a sneak peek of the Bridgerton books in order. However, navigating marriage and society is not always easy. It features eight siblings and their widowed mom. The series centers on the close-knit Bridgerton family, against the backdrop of Regency England’s upper society. Each book is about a different character finding their true love and overcoming obstacles. The Bridgerton series is by Julie Pottinger, an American historical romance author who uses the pseudonym Julia Quinn. Binged the Bridgerton series on Netflix and still wanting more? You’re probably finding yourself wanting to read all of Julia Quinn’s Bridgerton books in order. ![]() 9/6/2023 0 Comments Braided line eye splice![]() ![]() Keep the marks tightly together for the remainder of the splice procedure. Pull the ends of both the core and cover until the marks on the cover and core are adjacent to each other. Remove the fid and tape from the end of the cover. This will require bunching up the core back toward Core Mark 2.Pull the fid out of the core exposing the entire fid and as much of the cover tail as possible. Push the fid through the core for a distance of 1.5 fid lengths from Core Mark 2. I. Insert the fid into the core at Core Mark 2 ![]() H. Remove the fid from the bitter end of the core and tape it to the tapered bitter end of the cover. G. Trim each of the strand pairs at the point where they exit from the cover braid. Alternate counting and marking 5th and then 4th pick until you reach the end of the rope.į. Pull each of the marked strand pairs out from the end of the cover braid. Countdown 4 picks and mark the 4th pairĮ. Mark the 5th Pair to form a V Shaped Mark on the coverĭ. Start on Mark 1 and count 5 Picks toward bitter end of ropeĬ. Remove all tape from the bitter end of the cover.ī. STEP 2: SPLICING THE CORE & COVER TOGETHERĪ. Continue to push the fid about 1/3 fid length past Mark 2 and then exit the fid and core through the cover. *Reminder: Avoid snagging the core inside the cover with the tip of the fid. M. With the tip of fid positioned at the point of extraction, carefully continue to push the fid past Mark 2. L. Milk fid through cover braid until it reaches the point where the core was extracted from the rope - this is Mark 2 on the cover. K. Insert fid into the cover at Mark I toward Mark 2 J. Tape the fid to the bitter end of the core. H. Use Table Below and count prescribed number of picks from Core Mark 1 down toward the anchor point Pull the bitter end of the core out of the cover braid as well. Pull core our of cover from Mark 2 towards the hitch knock anchor pointī. This is Mark X (You will extract the core from inside the cover from here)Į. Use Fid to separate cover yarns at Mark 2 - this will expose the core.Ī. From Point R form a loop of the eye size desired and mark the line.ĭ. I. This creates your reference point aka Point “R”Ĭ. Measure 1 tubular fid length OR 2 wire fid lengths and mark line. Tape the end of line with one layer of tape.ī. ![]() *Reminder: All Splicing Should Be Performed On A Clean, Flat Surface.Ī. DOUBLE BRAIDED ROPE EYE SPLICE USER INSTRUCTIONS BY PELICAN ROPE With all of that being said, you also can download this guide here. It should be noted that splicing ropes will decrease the strength of the rope, especially if it is done improperly, so we really can’t stress enough that this guide is for informational purposes only and should not be seen as a substitute for guidance from an expert professional. While we always recommend seeking out professional guidance on any alterations made to ropes (especially if you are using them for work or heavy-duty applications), we did want to take some time to share our new guide on splicing Double Braid Ropes with you. Here at Pelican Rope, we like talking about ropes and splicing is sort of a passion project in our corner of the world. For those of you who are searching out how to splice rope, you have come to the right spot. ![]() 9/6/2023 0 Comments Keep undercover meaning![]() ![]() It is a reminder that even though she may keep her true feelings hidden, her loyalty and dedication are always present. Ultimately, "Keep It Undercover" showcases Zendaya's determination to face challenges head-on, maintain a strong and composed demeanor, and provide unwavering support to someone she deeply cares for. She promises to go to extraordinary lengths to be there for them and assures them that they need not worry. She expresses her availability, urging the person to reach out to her whenever they need assistance. The lyrics are about a person who is always there for their partner, even in dangerous situations, but they keep their abilities and strategies a secret. The undercover police made a drug bust last. Pertaining to anything with secret or clandestine overtones. The bridge reinforces Zendaya's reliability and willingness to help. To operate in a secret or clandestine fashion. She presents herself as genuine and fearless, assuring the person she is addressing that she will always support them. The scene is the same every time: They bend his ass over the hood of the car and say, 'You have the right to remain silent.' That phrase is like the cops end zone dance. because she ' might have given me away without meaning to do so. She lives her life with awareness and caution ("red alert"), always striving to make things work and be successful. After months of grueling investigation and forensic work, the police finally get enough evidence to put the drug kingpin behind bars. Rather disingenuously he blamed the undercover work for his 1946 divorce and for. ![]() The chorus emphasizes Zendaya's self-assured nature and her ability to handle difficult circumstances. However, she chooses to keep these thoughts hidden, "undercover." This suggests that she prefers to maintain a strong and composed appearance, even in challenging situations. In the verses and the pre-chorus, Zendaya acknowledges her imperfections and the things she wants to share with the person she is addressing. Throughout the song, Zendaya emphasizes her unwavering commitment to someone important to her and her determination to protect them without drawing attention to herself. Unfortunately, most states treat them as fair game for local enforcement. And in California, recently passed bills SB 741 and CalECPA limit the acquisition and use of IMSI catchers. The song "Keep It Undercover" by Zendaya is an anthem about maintaining resilience, strength, and loyalty in the face of danger or adversity. As of September, federal law enforcement agents can no longer use IMSI catchers without a warrant. ![]() ![]() Thus when you get to that site, you also need to make sure the video you get is of high quality. Quality is one of the factors that will make you opt for one site instead of the other. Quality videos – When downloading videos you also want to get the video with the highest quality. When new audio or video is uploaded, the software will download it automatically without having to wait for your command. 4k video downloader key allows you to register in a YouTube channel so that when any new video is uploaded, you are the first person to have it. The good thing is to look for a way in which you can automatically get these videos. Also at times, you may be busy, and you will miss videos when your favorite artists upload them. This software will allow you to access these restricted websites without having to install a VPN.Īutomatic downloading – Going to your favorite channel every time to check for new uploads can be much demanding. With 4k video downloader, the case is different as you will not need a VPN after you have downloaded this program. Many downloaders will not help you to hide your IP address, and you will need to install the downloader and a VPN at the same time. Doing all this can be more costly and going for a straight option will be beneficial. For you to access these websites, you will always need to go for an extra step and download a VPN so that you can change or hide your IP address. Surf restricted websites – Apart from restricting you to download videos from their sites, some websites will also limit people from certain geographical areas. The supported sites include Vimeo, Facebook, YouTube, Tumblr, SoundCloud, Flickr, and DailyMotion. The good thing is that this application will support all those popular video sites ensuring you will download whatever interest you there. To get the best you need to make sure you check on all these popular websites and download whatever you want. Each site has different artists, and each one of them will post a different thing. Not all that you find in one site will be on the other one. The program is not YouTube supported only. Support popular video sites – 4k video downloader key will support all the popular video sites that you know. After saving it will be easier to delete the ones you don’t want of which they will be the lesser ones. If you like a particular artist then you doesn’t need to struggle in downloading their video uploads, you just save their recent playlist or their whole channel. If you like a specific playlist or channel, you can save it as a whole and save yourself from that demanding activity. With 4k video downloader, you don’t have to keep coming back for one video or audio file at a time. This can be time consuming and boring at the same time. At times you may like many videos in a particular channel, and you have to keep downloading one video at a time. 4k Video Downloader Key Featuresīatch downloading – What makes this application different from other downloaders is that you can download your videos in batch form. 4k video downloader allows you to download several videos within a short time. The app will support 3GP, MKV, and MP4 for video files and OGG, M4A, and MP3 for audio files. If you are concerned to know which formats will be supported by this application, there are several formats. You can also download a whole playlist or YouTube channel using this software. You can download any video or audio file from the YouTube as you will only copy that link address and insert it to your application interface. Using this software is very simple as you only copy the link address to your clipboard and paste it at the app user interface. Your internet speed will remain high, and you can continue with other activities that may be using the same internet connection. The software is safe, and it will never interfere with your computer and other files security. ![]() 4K Video Downloader Crack Torrent + keygen Ĥk video downloader key is a download manager that specializes in videos, audio, and subtitles. So how do you bypass website restrictions and download these files? There are many programs that you can use to save these videos on your device, and 4k video downloader key is one of them. Downloading these videos and audios to your computer remains to be the only option you can go for. ![]() Sometimes you have to search for the video afresh which can be expensive and time taking. At times these videos might be much interesting, but you can’t save them on your device so you have to keep coming back to the website so that you can watch them. An excellent example of these sites is Daily Motion and YouTube. As you browse through the internet, you might have come through some websites that you can watch videos and listen to audios but without downloading them. ![]() 4k Video Downloader Key Crack + Torrent Free Download ĤK Video Downloader crack free for you. ![]() 9/6/2023 0 Comments Lorraine schwartz rings![]() ![]() ![]() ![]() Of all the stones she works with, Schwartz sees emeralds as her career-defining gems. “Lorraine girls are authentic, they’re real, they’re not wearing to impress or show off, they’re wearing because that’s who they are,” says Schwartz. Lady Gaga's heart-shaped engagement ring.ĮMERALDS ARE A LORRAINE GIRL’S BEST FRIEND Kim Kardashian's second engagement ring from Kanye West. Kim Kardashian's first engagement ring from Kanye West. ![]() Here are a few of her breathtaking bespoke engagement ring creations: Proud wearers of Lorraine Schwartz engagement rings include Lady Gaga, Beyoncé, Blake Lively, and Kim Kardashian West (to name a few). Since that fateful connection, she has become a much sought after designer for celebrity engagement rings in particular, and she even styled Monica and Chandler’s wedding for the television show Friends! “It was a 10-carat canary diamond, and it was a big sale for me,” she says. In fact, the designer tripped on a chair and fell directly into Bowie! Schwartz reminisces about how nervous she was going into that meeting. The sale ultimately led to Schwartz designing an engagement ring for his then-girlfriend, supermodel Iman. Schwartz has had countless celebrity clients over the years, including Sofia Vergara, Kim Kardashian West, Heidi Klum, Blake Lively, Sandra Bullock, Octavia Spencer, Elizabeth Taylor, Angelina Jolie, Oprah Winfrey, Barbra Streisand, Pharell Williams, and many others, but things really took off for the designer in 1994 when David Bowie approached her to purchase a large diamond. “What was so cool about her,” Schwartz continues, “was the way she would wear wood, jade, and raw crystal in a way that looked priceless.” Every time I get stuck on an idea, I think of her and inspiration comes to me.” “My mom was regal, impeccable,” she says. Influenced by impressionist art, the natural world, and certain fabrics, Schwartz cites her mother as her biggest inspiration to her work. “I started to create more unique, cool, funky high-end jewellery. In a bold-yet-savvy move, she renamed the company Lorraine Schwartz Diamonds & Fine Jewelry and completely reimagined its business model. When her mother died from cancer at age 55 in 1989, Lorraine became the third generation to take over her family’s diamond business. Lorraine Schwartz is an American designer of bespoke, high-end jewellery whose name, according to, is mentioned by celebrities on the red carpet more than any other brand or fashion house. Lorraine Schwartz s itting amongst some of her pieces. Read on to learn more about this enigmatic designer, her celebrity connections, and her incredible philanthropy! With eight to nine years under his belt at Lorraine Schwartz, this man knows a thing or two when it comes to choosing the perfect cut, so consider this your 101 guide to finding the *perfect* diamond.In honour of International Women’s Day on March 8th, we’ve decided to shine a spotlight on some of the talented women who have shaped the jewellery design industry over the years. Blake Lively with the oval shape, Beyoncé with the emerald cut’." Cohen, who buys, sources, and acquires the diamonds (along with other precious stones) says he finds cutting a diamond from rough start to shiny finish therapeutic. It’s no secret that Lorraine Schwartz is a celeb go-to for both engagement and wedding rings, as Cohen casually told us, "when Kim Kardashian wore the cushion cut we got a lot of phone calls because people wanted that shape. It’s not common to get such a special BTS look at these jewels, and we did not for one second take it for granted (we were pinching ourselves practically the whole time). We were lucky enough to sit down with President of Production at Lorraine Schwartz, Justin Cohen, to get a rare, up close and personal look at some of the incredible diamonds he works with on a daily basis. One of her ahem, more notable stones has been very much in the news lately. Unless you’ve been hiding under a rock (and we’re not talking diamonds), you’re familiar with Lorraine Schwartz. ![]() 9/6/2023 0 Comments Nuggets score yesterday![]() Jokic had 10 points, seven rebounds and three assists in the first quarter. He became the oldest player to appear in the NBA Finals, breaking the mark of 42 years, 58 days set by Kareem Abdul-Jabbar on June 13, 1989. Miami’s Udonis Haslem - in his 20th and final season - set a record. The Heat won Game 7 and went on to beat Oklahoma City for James' first title. Wednesday was the 11th anniversary of LeBron James' 45-point, 15-rebound, five-assist game at Boston in Game 6 of the East finals - staving off elimination. The Heat didn’t have any “home” games in the 2020 finals, which were held in the NBA’s restart bubble near Orlando. Heat: It was the first finals game in Miami since 2014. Jokic played in both of those games, Murray in the second one early in his rookie season. Denver hadn’t lost two consecutive games to Miami since March 14 and Nov. Nuggets: Denver used Reggie Jackson in the first quarter, going nine deep in the opening 12 minutes for the first time since Game 2 of the West finals. It was 53-48 at halftime, before Denver pushed the lead to double digits for the first time early in the third and wound up leading by as many as 19 later in that period. A dunk by Adebayo put the Heat up 44-42 with 3:18 left in the half, before a 3-pointer by Murray represented the seventh and final lead change of the night. Jokic finished 12 for 21 from the floor, 7 for 8 from the line, playing 44 minutes.Ĭhristian Braun was tremendous off the bench for the Nuggets, scoring 15 points on 7-for-8 shooting in 19 minutes. It was his 10th triple-double of these playoffs, extending his single-season record, and he was unbothered by whatever Miami threw his way. Draymond Green, Wilt Chamberlain, Larry Bird and Butler all had one title series with two triple-doubles. Magic Johnson and LeBron James each did it in three different finals. Officially, Jokic is now the seventh player to have two triple-doubles in the same finals. The Heat got within nine on a 3-pointer by Duncan Robinson with 1:22 left, but there was no epic finish for Miami. ![]() The lead eventually reached 21, the outcome never seriously in doubt, and Jokic looking very much like he's back in cruise control. “Tonight, we win the fourth quarter, we win the game.” “First two games, they won the fourth quarter,” Malone said. The Heat were down by 14 going into the fourth, and Nuggets coach Michael Malone reminded his club of Miami’s penchant for comebacks. Miami has been the comeback kings of these playoffs - seven rallies in games after trailing by at least 12 points. Jimmy Butler scored 28 points for Miami, and Bam Adebayo finished with 22 points and 17 rebounds. The Nuggets outrebounded the Heat 58-33, and took a 2-1 lead. Murray had 34 points, 10 rebounds and 10 assists, getting the rebound he needed with 9 seconds remaining. ![]() Jokic finished with 32 points, 21 rebounds and 10 assists - the first such game in NBA Finals history, or at least the first since assists were tracked. ![]() Nikola Jokic and Jamal Murray became the first teammates in NBA Finals history to both record triple-doubles, and Denver's two stars made sure the Nuggets reclaimed the lead in the series by beating the Miami Heat 109-94 in Game 3 on Wednesday night. ![]() 9/6/2023 0 Comments Marsupilami metacritic![]() ![]() And for the completionist, a beautiful artwork gallery will be unlocked after collecting hidden feathers and visiting secret dojos. While mainly targeting a younger audience, the most dedicated gamers would be delighted to learn a Time Attack mode will challenge them to finish each level as fast as they can. Jump, punch, dash and swing with your tail like only Marsupilamis do. Discover the Marsupilamis as you have never seen them before in an adventure full of. It is based on the comics series Marsupilami created by André Franquin. Fortunately for them, the Marsupilamis are immune. 48.4 million 1 Houba On the Trail of the Marsupilami (original title: Sur la piste du Marsupilami) is a 2012 Franco-Belgian CGI animated / live-action comedy film co-written and directed by Alain Chabat. While playing with debris on the beach, the three companions inadvertently open a cursed sarcophagus and release a mysterious ghost who places a terrible curse on all animals. + Outstanding platforming gameplay with an intuitive and satisfying move set. Marsupilami has been around a long time and the franchise now has a new 2D platformer thats absolutely wonderful so lets jump to it. Punch, Twister and Hope are three Marsupilamis who live a peaceful life in Palombia. Even after over 30 years of playing 2D platformers, it really took me back to why I love the genre with its intuitive and rewarding gameplay and cheerful presentation. Inspired by the comic book Marsupilami from Franquin, this 2.5D platformer will take you on a colorful journey through the Palombian jungle, a coastal city and even an abandoned temple. Marsupilami: Hoobadventure is one of those games that has no right to be as good as it is. Their lives are about to take a drastic turn when they accidentally open a sarcophagus whilst playing with debris on a beach, releasing a mysterious ghost cursing all the animals! Thankfully, our three Marsupilamis are immune to the curse and decide to set out on an adventure and find the ghost and reverse the curse. ![]() Their lives are about to take a drastic turn when they accidentally open a sarcophagus whilst playing with debris on a beach, releasing a mysterious ghost cursing all the animals! Thankfully, our three Punch, Twister and Hope are three Marsupilamis living a peaceful life in Palombia. ![]()
9/6/2023 0 Comments Red crucible 3 much games![]() ![]() It is extremely biased in favour of the attacking team. The addition of respawns has made the mode cheesy as all fuck, especially on larger maps. Who finally got a PS4? Norsefenrir! Happy birthday!Ĭountdown in Labs would be a disaster along the lines of Rift if it makes it into comp or Trials without being changed. Who finally got a PS4? >!Norsefenrir! Happy birthday!!< Spoiler Formattingīegin your title with the tag "". Players of all platforms are welcome here, bullying is not.įull Subreddit Rules For a list of retired suggestions, see our BungiePlz Wiki FiltersĬonfused? An exclusion filter allows a flair to be hidden from your browsing experience. Insults, personal attacks, condescension, or similar behavior relating to the merits of platform choice will not be tolerated. For more info on the rules of charity events see this page. For more info on the rules of giveaways see this page. Any user who wishes to make a giveaway, contest (with prizes), or charity post must receive approval from moderators BEFORE making the post. No advertising, selling, trying to buy, trading, or begging. Absolutely no linking to livestreams, except official Bungie streams or past broadcasts. Self-promotion should be thoughtful, limited, and consistently well received by the community. For further examples see our wiki.ĭon't spam. Examples include posts with spoilers in the title, comments with unmarked spoilers, clickbait titles, "Does Anyone Else" posts or posts with title tags. ![]() Marginal Content: Content must be properly flaired and formatted. Examples include LFG posts, memes, content relating to an Active Megathread, loot posts, Petition Posts or Technical Issues. Misplaced Content: Content must be posted to the correct Place. Moderator discretion may be used for this rule. Unsuitable Content: Posts that are subject to removal are: retired suggestions, not directly related personal stories, recent reposts, low-effort/low-quality posts or posts not directly related to Destiny. ![]() Report players to Bungie In-Game or via this contact form. Absolutely no harassment, witchhunting, sexism, racism or hate speech will be tolerated. Keep it civil and do not make personal attacks or use offensive language in addressing others. Keep it Civil: Follow proper Reddiquette when submitting and commenting. Weekly Reset in 2 days 1 hours 31 minutes Daily Reset in 1 hours 31 minutes Community Links Light Mode Become a Guardian of the Light Daily Reset Thread | Daily Questions | Bungie Plz | Bungie's New Player Guide (Lightfall) | State of the Game | Focused Feedback: Monetization: Eververse Perks and Abilities Spreadsheet with Numbers.Buffs and Debuffs - The Statistical Spreadsheet.Destiny 2: Known Issues (Comprehensive).Sunday Plz - Give us an all black (Superblack) shader!.MUCHGAMES SHOULD ONLY BE USEDįOR ENTERTAINMENT PURPOSES AND AGAIN OFFERS NO REAL-WORLD PRIZES OR INCENTIVES. THE PURPOSE OF THIS IS TOĮNTERTAIN ITS USERS, AND PROVIDE AN APP WITH WHICH, USERS CAN TEST THEIR TABLE GAMING SKILLS FOR FREE. THE SITE OR APP DOES NOT PROVIDE ANY REAL-MONEY WINNINGS FROM THE COLLECTION OF GAMES IT HAS ON OFFER. MuchGames PROVIDES IT'S USERS WITH ACCESS TO A HUGE COLLECTION OF FREE-TO-PLAY SOCIAL CASINO GAMES. Share photos, customize your gamer profile, draw sketches, make friends, start private chats, exchange gifts and keep track of what yourĬopyright © 2023. When you sign up as a member, you get to discover the social community part of the site which offers you the ability to upload and Play games, rate them, post comments, add them to your favorites, share them and chat with other online gamers.įurthermore, we add new Two-Player Games every day so you can play against your friends. We add new games like Red Crucible 3e every day. With over 20,000 games to play, you should never get bored again. Welcome to, largest gaming social community on the net. ![]() 9/6/2023 0 Comments Inpaint 6.0![]() ![]() Metal carboxylates are also formed between terpenoid acids-deriving from plant resins used in coatings, varnishes and as ingredients of paint binders, and certain cations, as it has been discussed in several publications. ![]() Moreover, in manufactured oil paint formulations, since the 19th century, metal soaps (most commonly Zn and Al stearates) have commonly been added to facilitate the dispersion of pigments into the medium. Metal soaps are known to be spontaneously formed in artistic oil paintings, as a product of reaction between the excess of carboxylic acid moieties released by the hydrolysis of triglycerides as well as the oxidative cleavage of unsaturated fatty acids, and the metal ions contained in certain pigments. The method was then applied to the characterization of samples collected from two reference paint layers aged for 20 years, a paint sample taken from a pulpit, and sample of the varnish coating of a wooden writing desk, both from the second half of the seventeenth century. The application of this approach is possible because of the good stability at room temperature of the TMS derivatives of aliphatic and terpenoid species, characterized by high boiling points and relatively low vapour pressures. This is based on a two-step analytical approach entailing the subsequent use of two silylating agents, N, O-bis(trimethylsilyl)trifluoroacetamide for the analysis of free acids and metal carboxylates, and 1,1,1,3,3,3-hexamethyldisilazane for the analysis of free acids. In this paper we present an optimization and the validation of a GC/MS method for the qualitative and quantitative analysis of mixtures of terpenoid acids and aliphatic mono and dicarboxylic acids and metal carboxylates of terpenoid and aliphatic mono and dicarboxylic acids in the same paint microsample. Metal soaps and resinates are known to be spontaneously formed in artistic paintings, as a product of the reaction between aliphatic and terpenoid acids released by hydrolysis and oxidation of the organic media and certain cations contained in some inorganic pigments. ![]() |
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